LiFePO4 vs lead-acid (AGM and flooded) for solar

The battery chemistry decides how big a bank has to be, how much it weighs, how it charges and how long it lasts. Here is how lithium iron phosphate (LiFePO4) and lead-acid — flooded and AGM — compare, using figures from Victron, Trojan and Crown documents rather than marketing claims.

Side by side

From Victron’s Lithium Battery Smart manual and Energy Unlimited book, Trojan’s 27TMX data sheet and FAQs, and Crown’s deep cycle specifications.
LiFePO4Lead-acid (flooded, AGM, gel)
Usable capacity used for sizingAbout 80% (Victron rates cycle life at 80% DoD)About 50% (Trojan recommends 20–50% discharge)
Usable energy, 12 V 100 AhAbout 1,024 Wh (12.8 V × 100 Ah × 80%)About 600 Wh (12 V × 100 Ah × 50%)
Cycle life2,500 cycles at 80% DoD, 5,000 at 50% (Victron, to 80% capacity)Depends heavily on type and depth — check the data sheet; ageing speeds up sharply past about 80% DoD (Victron)
Round-trip efficiency92% (Victron)About 75% full cycles, about 89% in partial-charge use (Victron)
Weight, group 24 size27.6 lb for 100 Ah (Crown V12-100)50 lb for 90 Ah flooded (Crown 24HDC)
Capacity at high currentHolds up well within its rated currentFalls: Trojan 27TMX gives 85 Ah over 5 h vs 105 Ah over 20 h
Charging temperatureOnly +5 °C to +50 °C (Victron)Wider; flooded −20 °C to +45 °C (Trojan), keep above 60% charge below freezing
Needs a management systemYes — Victron requires an approved BMSNo
MaintenanceNoneFlooded: check water; AGM/gel: none
Self-dischargeLow — check the data sheet5–15% a month (Trojan)

Usable capacity is the big difference

Both chemistries are sold in amp-hours, but you can use far more of a lithium battery. Victron rates its LiFePO4 batteries for 2,500 cycles at 80% depth of discharge; Trojan generally recommends discharging lead-acid only 20–50% of its rating for long life, even though it can be cycled to 80%. So a 100 Ah LiFePO4 battery does roughly the work of 170 Ah of lead-acid. For the arithmetic, see how many watt-hours in a 100Ah battery; for what it means in hours, how long a 100Ah battery runs a fridge and how long a 100Ah battery lasts with a 200W load.

Heavy loads and inverters

Lead-acid loses capacity as current rises. Trojan’s group 27 data sheet shows 105 Ah over 20 hours but only 85 Ah over 5 hours; an inverter running a microwave discharges far faster than that. LiFePO4 holds up better — Victron rates its LiFePO4 capacity at a 1C discharge, 100 A for a 100 Ah battery — but has a different limit — the battery management system’s current rating. Victron recommends no more than 100 A continuous from its 12.8 V 100 Ah battery, so big 12 V inverters need several batteries in parallel either way: see what size battery bank for a 3000W inverter.

Cold weather

  • Charging LiFePO4 below freezing damages it. Victron allows charging only between +5 °C and +50 °C (discharging from −20 °C). In cold climates, lithium banks live indoors, in heated compartments, or use self-heating models and chargers that stop when the BMS says so.
  • Both lose capacity in the cold. Victron says its LiFePO4 capacity is about 20% lower at 0 °C and about half at −20 °C.
  • Lead-acid can freeze when flat. Trojan gives about 16 °F (−9 °C) as the freezing point at 40% charge — keep lead-acid charged in winter.

Charging differences

LiFePO4 accepts charge efficiently. Lead-acid needs a long finish: the last part of the charge runs at falling current, and Trojan warns that operating in a partial state of charge causes sulfation and early failure. In a solar system that means lead-acid needs enough panel to reach full charge regularly. Use charger settings from the battery’s data sheet — Victron gives 14.2 V charge and 13.5 V float for its 12.8 V batteries; Trojan’s flooded 27TMX uses 14.82 V bulk and 13.50 V float. How long a 100W solar panel takes to charge a 100Ah battery compares the two.

Safety

  • Lead-acid gives off hydrogen when charging. Trojan: don’t install or charge batteries in a sealed or unventilated compartment.
  • Lithium needs its BMS. Victron’s manual warns that overcharge or deep discharge can make a lithium battery unsafe, and requires an approved battery management system and safety relay.
  • Both can deliver huge short-circuit currents. Cover terminals, don’t lay tools on top, and remove rings and watches when working on them.
  • Fuses and wire come from NEC/ABYC ampacity tables and the equipment manual — have a qualified installer check them.

More on handling and charging safely is in the battery safety guide.

Which to choose

  • LiFePO4 when weight, space and daily cycling matter — vans, boats, RVs that boondock, off-grid cabins used most days — and when you can keep it above freezing while charging.
  • AGM for occasional use, cold storage, or as a lower-cost upgrade over flooded with no maintenance.
  • Flooded for budget banks that are checked and watered, and in places where weight doesn’t matter.
CalculatorBattery Bank Size Calculator →Size the bank in either chemistry.

Frequently asked questions

Is LiFePO4 better than AGM for solar?

For daily cycling, usually: you can use about 80% of it versus about 50% of AGM, it is roughly half the weight for the same capacity, and Victron rates it for 2,500 cycles at 80% depth of discharge. AGM is simpler in freezing conditions and cheaper up front.

Can I charge a LiFePO4 battery below freezing?

Not unless the battery is designed for it. Victron allows charging only between +5 °C and +50 °C; self-heating batteries warm themselves first.

Can I mix lithium and lead-acid batteries?

Not in the same bank. They charge at different voltages and share load unevenly; mixing them can shorten the life of both.

How much lighter is a lithium battery?

In Crown’s data, a group 24 LiFePO4 battery (100 Ah) weighs 27.6 lb against 50 lb for its group 24 flooded deep cycle battery (90 Ah).

Sources